Spatiotemporal Variation of Zn Speciation and Its Effect on Available Zn in Cinnamon Soil under Long-term Fertilization

doi:10.7668/hbnxb.20191584

Abstract

Abstract: In order to investigate the variation of Zn speciation in cinnamon soil under different long-term fertilization and its effect on available Zn, the cinnamon soil in Shanxi Province was taken as the research object. The change process of soil available Zn and the temporal and spatial variation of different forms of Zn under different fertilization conditions were studied by classifying and measuring 9 soil samples in a continuous 27-year long-term fertilizer localization experiment. The relationship between different forms of Zn and available Zn was analyzed. The results showed that, except N₂P₂, the soil available Zn content had no significant change compared with the beginning of the experiment. After 27 years of continuous fertilization, the soil available Zn content ranged from 0.72 to 0.84 mg/kg.The application of organic fertilizer significantly increased the soil available Zn content (P<0.05), and the annual increase rates of soil available Zn content in N₂P₁M₁, N₃P₂M₃ and N₄P₂M₂ treatments were 0.057, 0.151,0.074 mg/(kg·a), respectively.The soil available Zn reached 7.37 mg/kg with high amount of organic fertilizer M₆ treatment, far exceeding the soil nutrient grading standard in China.Correlation analysis and path analysis showed that the reducible Zn in soil was the main source of available Zn in cinnamon soil, and the significant positive correlation between water-soluble Zn, weakly acid soluble Zn and available Zn was caused by indirect effect.Therefore, promoting the conversion of Zn to water-soluble Zn, weakly acid soluble Zn and reducible Zn can increase the content of available Zn in soil and promote the efficient utilization of Zn.

Key words: Cinnamon soil, Available Zn, Zn form, Grading determination, Correlation analysis, Path analysis

CLC Number:

YANG Zhenxing, ZHOU Huaiping, XIE Wenyan, LIU Zhiping. Spatiotemporal Variation of Zn Speciation and Its Effect on Available Zn in Cinnamon Soil under Long-term Fertilization[J]. ACTA AGRICULTURAE BOREALI-SINICA, 2021, 36(2): 162-168. doi: 10.7668/hbnxb.20191584.

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References

[1] 甘万祥,高巍,刘红恩,王巧燕,赵鹏.锌肥施用量及方式对夏玉米籽粒淀粉含量和产量的影响[J].华北农学报,2014,29(6):202-207.doi:10.7668/hbnxb.2014.06.034.
Gan W X, Gao W, Liu H E, Wang Q Y, Zhao P. Effects of different ways of applying zinc fertilizer and the amount of zinc fertilizer on the content of starch in summer maize and yield of summer maize[J]. Acta Agriculturae Boreali-Sinica,2014,29(6):202-207.
[2] 车丽,韩彦青,杨丽.锌锰肥对春玉米产量及品质的影响[J].山西农业科学,2019,47(11):1980-1983.doi:10.3969/j.issn.1002-2481.2019.11.26.
Che L, Han Y Q, Yang L. Effects of zinc and manganese fertilizer on yield and quality of spring corn[J]. Journal of Shanxi Agricultural Sciences,2019,47(11):1980-1983.
[3] 王俊梅. 长期施肥对棕壤Zn、Cu形态转化和作物吸收的影响[D].沈阳:沈阳农业大学,2017.
Wang J M. Effects of long term fertilization on Zn, Cu transformation and crop uptake in brown soil[D].Shenyang:Shenyang Agricultural University,2017.
[4] 王美,李书田,马义兵,黄绍敏,王伯仁,朱平.长期不同施肥措施对土壤铜、锌、镉形态及生物有效性的影响[J].农业环境科学学报,2014,33(8):1500-1510.doi:10.11654/jaes.2014.08.006.
Wang M, Li S T, Ma Y B,Huang S M, Wang B R, Zhu P. Influence of different long-term fertilization practices on fractionations and bioavailability of Cu, Zn, and Cd in soils[J]. Journal of Agro-Environment Science,2014,33(8):1500-1510.
[5] 陆欣春,邹文秀,韩晓增,郝翔翔,江恒.长期施肥对黑土磷和锌形态转化的影响[J].植物营养与肥料学报,2015,21(6):1536-1542.doi:10.11674/zwyf.2015.0620.
Lu X C,Zou W X,Han X Z, Hao X X,Jiang H. Effect of long-term fertilization on phosphorus and zinc fractions in a mollisol[J]. Journal of Plant Nutrition and Fertilizer,2015,21(6):1536-1542.
[6] Stephan C H, Courchesne F, Hendershot W H, McGrath S P, Chaudri A M, Sappin-Didier V, Sauvé S.Speciation of zinc in contaminated soils[J]. Environmental Pollution,2008, 155(2):208-216. doi:10.1016/j.envpol.2007.12.006.
[7] 白玲玉,陈世宝,华珞,韦东普.腐植酸与Cd、Zn的络合特性研究[J].核农学报,2000,14(1):44-48.doi:10.3969/j.issn.1000-8551.2000.01.010.
Bai L Y, Chen S B,Hua L,Wei D P. Studies on characteristics of complexation of Cd and Zn with humic acids[J]. Acta Agriculturae Nucleatae Sinica,2000,14(1):44-48.
[8] Ramzan S, Bhat M A, Wani M A. Distribution of chemical pools of soil zinc under various land use systems[J]. Journal of Renewable Agriculture, 2013,1(4):52-62.doi:10.12966/jra.07.01.2013.
[9] Jalali M, Khanlari Z V. Effect of aging process on the fractionation of heavy metals in some calcareous soils of Iran[J]. Geoderma,2008,143(1-2):26-40.doi:10.1016/j.geoderma.2007.10.002.
[10] 杨振兴,周怀平,解文艳,刘志平.长期施肥褐土不同磷组分对磷素盈余的响应[J].植物营养与肥料学报,2020,26(5):924-933.
Yang Z X, Zhou H P, Xie W Y,Liu Z P. Response of phosphorus components to phosphate surplus in cinnamon soil under long-term fertilization[J]. Journal of Plant Nutrition and Fertilizers,2020,26(5):924-933.
[11] 杨振兴,周怀平,解文艳,刘志平.长期施肥对褐土有机质、氮动态变化的影响[J]. 山西农业科学,2019,47(12):2131-2134.
Yang Z X, Zhou H P, Xie W Y, Liu Z P. Effect of long-term fertilization on organic matter and N dynamic changes in cinnamon soil[J]. Journal of Shanxi Agricultural Sciences,2019,47(12):2131-2134.
[12] 杜艳玲,周怀平,杨振兴,程曼,解文艳,郭晋,王志伟.长期施肥下褐土中不同磷组分对磷素盈余的响应[J].华北农学报,2018,33(3):224-231.doi:10.7668/hbnxb.2018.03.033.
Du Y L, Zhou H P, Yang Z X, Cheng M, Xie W Y, Guo J, Wang Z W. Response of different P component to P balance in cinnamon soil under long-term fertilization[J]. Acta Agriculturae Boreali-Sinica, 2018,33(3):224-231.
[13] 杜家菊,陈志伟.使用SPSS线性回归实现通径分析的方法[J].生物学通报,2010,45(2):4-6.
Du J J, Chen Z W.The method of path analysis using SPSS linearregression[J]. Bulletin of Biology,2010,45(2):4-6.
[14] 王书转.长期施肥条件下土壤微量元素化学特性及有效性研究[D].北京:中国科学院大学,2016.
Wang S Z. Availability and chemical characteristics of trace elements in soils under long-term fertilization[D]. Beijing:University of Chinese Academy of Sciences, 2016.
[15] 黄德明,徐秋明,李亚星,姚志东.土壤氮、磷营养过剩对微量元素锌、锰、铁、铜有效性及植株中含量的影响[J].植物营养与肥料学报,2007,13(5):966-970. doi:10.3321/j.issn:1008-505x.2007.05.032.
Huang D M, Xu Q M, Li Y X,Yao Z D. Influence of soil N and P excess on the availability of Zn,Mn,Fe,Cu and there content in plant[J]. Journal of Plant Nutrition and Fertilizers,2007,13(5):966-970.
[16] 聂兆君,秦世玉,王媛,刘红恩,赵鹏. 施氮量对石灰性潮土锌吸附和解吸特性的影响[J]. 河南农业大学学报,2019,53(1):135-141.doi:10.16445/j.cnki.1000-2340.2019.01.020.
Nie Z J, Qin S Y, Wang Y, Liu H E, Zhao P. The effect of nitrogen application on adsorption and desorption characteristics of zinc in calcareous fluvo-aquic soil[J]. Journal of Henan Agricultural University,2019,53(1):135-141.
[17] Mortvedt J J, Giordano P M, Lindsay W L. Interactions of micronutrients[M]//Micronutrients in agricultural. Beijing:Agriculture Press,1984:194-196.
[18] 杨玉爱,王珂,叶正钱,魏幼璋.有机肥料资源及其对微量元素的螯溶和利用的研究[J].土壤通报,1994,25(7):21-25,27.doi:10.19336/j.cnki.trtb.1994.s1.007.
Yang Y A, Wang K, Ye Z Q, Wei Y Z. Study on the resources of organic fertilizer and its application to micronutrient[J]. Chinese Journal of Soil Science,1994,25(7):21-25,27.
[19] 王擎运,张佳宝,赵炳梓,邓西海,信秀丽,钦绳武.不同施肥方式对典型壤质潮土中微量元素积累及其有效性的影响[J].土壤学报,2012,49(6):1104-1113.
Wang Q Y, Zhang J B, Zhao B X, Deng X H, Xin X L,Qin S W. Influence of different long-term fertilization practices on accumulation and availability of micronutrients in typical loamy fluvo-aquic soil[J]. Acta Pedologica Sinica,2012,49(6):1104-1113.
[20] 许浩,韩丽媛,茹淑华,张云青,苏德纯.不同有机肥中Cu、Zn在农田土壤中的有效性与形态归趋[J].植物营养与肥料学报,2016,22(4):998-1009.doi:10.11674/zwyf.15398.
Xu H, Han L Y, Ru S H, Zhang Y Q, Su D C.Bioavailability and form tendency of Cu and Zn in farmland soils after application of different organic fertilizers[J]. Journal of Plant Nutrition and Fertilizers, 2016,22(4):998-1009.
[21] Tabassum S, Jeet S, Kumar R, Dev C M, Kumar P, Rehana R. Effect of organic manure and zinc fertilization on zinc transformation and biofortification of crops in vertisols of central India[J]. Journal of Agricultural Science, 2014,6(8):221-231.doi:10.5539/jas.v6n8p221.
[22] 王凤仙.长期施肥对黑土锌形态转化及其生物有效性的影响[D].哈尔滨:东北农业大学,2010.doi:10.7666/d.y1787169.
Wang F X. Effect of long-term fertilization on transformation and bioavailability of zinc in black soil[D]. Harbin:Northeast Agricultural University,2010.
[23] 张艺腾,范禹博,徐笑天,张秀芳,李明堂.鸡粪生物炭对土壤铜和锌形态及植物吸收的影响[J].农业环境科学学报,2018,37(11):2514-2521.doi:10.11654/jaes.2018-0390.
Zhang Y T, Fan Y B, Xu X T, Zhang X F, Li M T.Effects of chicken manure-derived biochar on Cu and Zn speciation in soil and uptake by plant[J]. Journal of Agro-Environment Science,2018,37(11):2514-2521.
[24] 郝佳丽,卜玉山,贾峥嵘,席吉龙,姚景珍,段超.不同有机物料与外源锌对土壤锌形态及生物有效性的影响[J].农业资源与环境学报,2015,32(3):263-268.doi:10.13254/j.jare.2014.0298.
Hao J L, Bu Y S, Jia Z R, Xi J L, Yao J Z, Duan C.Effects of different organic materials and exogenous Zn on Zn distribution in soil[J]. Journal of Agricultural Resources and Environment,2015,32(3):263-268.
[25] 高焕梅.长期施肥对紫色土作物重金属含量的影响[D].重庆:西南大学,2008.doi:10.7666/d.y1263071.
Gao H M. Effects of long-term fertilization on heavy metal content in purple soil and crop[D]. Chongqing:Southwest University,2008.

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